I just recently heard this song and the radio and immediately loved it. Electric Guest is an L.A. based band made up of Asa Taccone on vocals and keyboard, Matthew Compton on guitar, bass, and drum, and Brian Burton as producing and songwriting collaborator in the studio.
They are currently touring in Europe before coming back to the U.S. for Sasquatch and Outer Lands. Their first album just came out recently, and covers quite a bit of ground. "This Head I Hold" is quite upbeat, and actually reminds me a little of Janelle Monae's "Tightrope."
Band image via.